Synthesis of a N-doped mesoporous carbon as an efficient electrocatalyst for oxygen reduction

A facile and effective approach was developed for the preparation of mesoporous Fe-NC by pyrolyzing the mixture of FeCl₂, urea, (NH₄)₂MoO₇, phthalic anhydride and SBA-15, during which the in-situ formation of iron phthalocyanine is confirmed. The obtained catalyst exhibits high catalytic activity towards ORR, whose half-wave potential can be 53 mV more positive than that of commercial Pt/C catalyst. Besides, the catalyst also exhibits high selectivity of four electron path, along with excellent stability and methanol tolerance in alkaline media. Based on the characterization results, we suggest, the higher surface areas, highly porous structures induced by SBA-15 addition, as well as high graphitic N content should be the proper origins for its outstanding catalytic performance.     

基于几何相位的线偏振聚焦超表面器件

设计出基于几何相位的介质超表面实现线偏振光聚焦功能。该设计打破了传统设计中几何相位(Pancharatnam-Berry phase)的手性限制,不再是局限于左旋圆偏振光(LCP)和右旋圆偏振光(RCP)入射。通过有限时域差分仿真来证明这种线偏振聚焦相位调控的特性。该类功能器件可能用于设计新颖的THz元器件、高分辨成像、功能探测等方面。     

厚煤层一次采全高煤壁失稳原因及控制技术

针对成庄煤矿四盘区层一次采全高煤壁失稳问题,对观测统计数据进行分析,发现片帮主要表现形式分五种:顶部、腰部、顶底部、底部以及斜切片帮,据此采用对顶板超前预爆破和煤壁超前预加固技术来控制大采高煤壁稳定性,不仅对煤壁失稳的控制取得了良好的效果,而且经济效益显著。可为相似条件下的厚煤层一次采全高煤壁失稳控制提供借鉴。     

综放工作面上隅角瓦斯治理技术实践

为解决瓦斯矿井综放面推采过高瓦斯区域时,上隅角瓦斯易超限的问题,结合赵庄二号井2309工作面地质情况,研究实施了工作面采空区瓦斯抽采和上隅角软管抽放的综合治理技术。实践表明:在2309综放工作面回采期间,上隅角瓦斯浓度得到有效控制,平均为0.15%,最高为0.36%,为工作面安全生产提供了有力保障。     

能源互联网内多类设备协同运行的能量管理系统软件设计

针对能源互联网中的海量分布式设备和电动汽车的需求，利用C#和Java编程语言设计并开发面向能源互联网的能量管理系统。该系统采用典型B/S 架构，以Asp.Net动态网页开发技术和数据库技术为核心，由云端后台算法、云端服务器的MySQL数据库、前端的网页三大部分构成。详细介绍了软件平台的系统框架，分为上下两层。其中，上层为日前-实时协同的多时间尺度能量管理系统模块，下层包含分布式设备协调控制子系统和电动汽车协调控制子系统。最后，通过仿真算例分析，能量管理系统能对海量的分布式设备和电动汽车进行优化调度，验证了该软件的可移植性、有效性和实用性。     

榆神矿区煤炭开采的地下水动态演化规律

榆神矿区浅表层水资源短缺,生态脆弱,在划分主采煤层上覆含、隔水层组合类型的基础上,采用Visual Modflow软件构建煤层开采的地下水流数值模型,研究地下水流场演化规律,统计区内地下水位观测网(56个水文观测孔)近3年的有效观测数据,掌握首采煤层开采地下水位动态变化。结果表明:2020年第四系萨拉乌苏组潜水流场与2005年统测地下水流场形态基本一致,地下水位降深值在西南部达10 m;近3年的地下水位未发生明显变化,仅YS22钻孔处受村民井取水引起水位下降。研究成果对榆神矿区地下水资源保护与利用具有重要的指导意义。     

大学生信守社会主义核心价值观“三自”理性演进论——基于主体能动价值的实现

依据马克思主义哲学观对人的主体能动价值实现的条件，联系高校对大学生社会主义核心价值观培育的实践，尊重、培育、强化大学生信守社会主义核心价值观的主体性就应当基于其主体能动价值的实现，应当尊重、培育、强化自为、自觉、自由的“三自”理性的能动性，使之信守社会主义核心价值观的“三自”理性能动性向着由高校引领的方向演进。     

Control of the particle microstructure during the synthesis of bulk-polymerized transparent methacrylate-acrylonitrile-butadiene-styrene resin

A series of methacrylate-acrylonitrile-butadiene-styrene (MABS) resins was prepared using bulk polymerization. The polarity of the continuous phase and the compatibility of two phases were changed by adjusting the methyl methacrylate (MMA) content, choosing values that were close to styrene-butadiene rubber solubility value. The possibility of controlling the microstructure of the MABS resin by changing the polarity of the components and the compatibility of two phases was assessed. The dynamic mechanical analysis shows that the compatibility of two phases varies with the MMA content. The morphological analysis shows that increasing MMA contents results in a gradual decrease in the sub-inclusion structure with a network skeleton of rubber particles, and that all the particles become solid rubber when the MMA content reaches 75%. The sub-inclusion structure reappears but does not have a network skeleton when the MMA content is 90%. The impact strength and morphological analysis indicate that the solid rubber particles and the sub-inclusion structure with a network skeleton provide excellent toughness, while the sub-inclusion structure without a network skeleton does not. In contrast, the transmittance of the ABS resin first increased and then decreased with increasing MMA content.     

Al2O3 loss prediction model of selective laser melting Al2O3–Al composite

The element/phase loss is undesirable but existing during selective laser melting (SLM) of materials with volatile element/phase, which not only changes the material composition but also affects the molten pool flow. In the previous researches, the effect of remelting on the element/phase loss was neglected during the SLM process, instead, laser energy density was thought to be uppermost. In fact, the SLM process fabricates the parts in a manner of line by line and layer by layer, i.e., additive character, and the remelting in the overlap zone occurs during the SLM process. In this paper, three different Al₂O₃ loss prediction models of SLM Al₂O₃–Al composite by considering the additive character of SLM and the distribution of the Al₂O₃ associated with the different molten pool driving forces were developed. By comparing with the experimental results and predicted results, it is found that the Al₂O₃ is distributed on both sides of the molten pool under the combined action of the Marangoni flow and the evaporation recoil pressure. This kind of Al₂O₃ distribution enhances the effect of the remelting on the Al₂O₃ loss, i.e., the remelting brings a logarithmic increase in the Al₂O₃ loss rate. This determines the final Al₂O₃ loss rate of the SLMed 3D samples. During this study, although the Al₂O₃ loss rate of the single-track is only 33%, the loss rate of SLMed 3D samples increases significantly to 97% when the hatching space of 60 μm and scanning speed of 200 mm/s are utilized, i.e., almost no Al₂O₃ in the 3D sample. Thus, it is more important to reduce the remelting, i.e., overlap rate for reducing the element/phase loss. This study is a benefit for understanding and reducing the element/phase loss in SLM.